{"id":92156,"date":"2026-04-21T07:00:57","date_gmt":"2026-04-21T07:00:57","guid":{"rendered":"https:\/\/gaeatech.com\/knowledge-center\/?p=92156"},"modified":"2026-04-13T23:38:12","modified_gmt":"2026-04-13T23:38:12","slug":"pollutev10-example-2-pure-diffusion-soil-model","status":"publish","type":"post","link":"https:\/\/gaeatech.com\/knowledge-center\/pollutev10-example-2-pure-diffusion-soil-model\/","title":{"rendered":"POLLUTEv10 Example 2: Pure Diffusion in a Soil Layer (No Sorption)"},"content":{"rendered":"\n<p>This example is a fundamental case used to demonstrate <strong>pure diffusion of a conservative contaminant<\/strong> through soil. Unlike more complex landfill scenarios, this example isolates <strong>diffusion-only transport<\/strong>, making it ideal for understanding baseline contaminant migration behavior.<\/p>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-overview-of-the-scenario\">Overview of the Scenario<\/h2>\n\n\n\n<p>In this example, contaminant transport occurs through:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>A <strong>4 m thick soil layer<\/strong><\/li>\n\n\n\n<li>A <strong>constant concentration source at the top boundary<\/strong><\/li>\n\n\n\n<li>An underlying aquifer where:\n<ul class=\"wp-block-list\">\n<li>Concentration is assumed to be <strong>zero (perfect sink)<\/strong><\/li>\n\n\n\n<li>Due to <strong>high flushing velocity<\/strong>, the aquifer is not explicitly modeled<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n\n\n\n<p>Key simplifications:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>\u274c No advection (Darcy velocity = 0)<\/li>\n\n\n\n<li>\u274c No sorption (Kd = 0)<\/li>\n\n\n\n<li>\u2705 Transport driven entirely by <strong>molecular diffusion<\/strong><\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-conceptual-model\">Conceptual Model<\/h2>\n\n\n\n<p>The system represents a classic <strong>one-dimensional diffusion problem<\/strong>:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Top boundary \u2192 constant concentration source<\/li>\n\n\n\n<li>Bottom boundary \u2192 zero concentration (instant removal)<\/li>\n\n\n\n<li>Transport mechanism \u2192 <strong>Fickian diffusion<\/strong><\/li>\n<\/ul>\n\n\n\n<p>This setup is widely used in environmental engineering to:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Validate numerical models<\/li>\n\n\n\n<li>Understand contaminant lag times<\/li>\n\n\n\n<li>Benchmark analytical solutions<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-input-parameters\">Input Parameters<\/h2>\n\n\n\n<figure class=\"wp-block-table\"><table><thead><tr><th>Property<\/th><th>Symbol<\/th><th>Value<\/th><th>Units<\/th><\/tr><\/thead><tbody><tr><td>Darcy Velocity<\/td><td>va<\/td><td>0<\/td><td>m\/a<\/td><\/tr><tr><td>Diffusion Coefficient<\/td><td>D<\/td><td>0.01<\/td><td>m\u00b2\/a<\/td><\/tr><tr><td>Distribution Coefficient<\/td><td>Kd<\/td><td>0<\/td><td>cm\u00b3\/g<\/td><\/tr><tr><td>Soil Porosity<\/td><td>n<\/td><td>0.4<\/td><td>&#8211;<\/td><\/tr><tr><td>Dry Density<\/td><td>\u03c1d<\/td><td>1.5<\/td><td>g\/cm\u00b3<\/td><\/tr><tr><td>Soil Thickness<\/td><td>H<\/td><td>4<\/td><td>m<\/td><\/tr><tr><td>Sub-layers<\/td><td>&#8211;<\/td><td>4<\/td><td>&#8211;<\/td><\/tr><tr><td>Base Concentration<\/td><td>cb<\/td><td>0<\/td><td>g\/L<\/td><\/tr><\/tbody><\/table><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-governing-equation\">Governing Equation<\/h2>\n\n\n\n<p>Transport is governed by <strong>Fick\u2019s Second Law of Diffusion<\/strong>:<\/p>\n\n\n\n<p><math xmlns=\"http:\/\/www.w3.org\/1998\/Math\/MathML\"><semantics><mrow><mfrac><mrow><mi mathvariant=\"normal\">\u2202<\/mi><mi>C<\/mi><\/mrow><mrow><mi mathvariant=\"normal\">\u2202<\/mi><mi>t<\/mi><\/mrow><\/mfrac><mo>=<\/mo><mi>D<\/mi><mfrac><mrow><msup><mi mathvariant=\"normal\">\u2202<\/mi><mn>2<\/mn><\/msup><mi>C<\/mi><\/mrow><mrow><mi mathvariant=\"normal\">\u2202<\/mi><msup><mi>x<\/mi><mn>2<\/mn><\/msup><\/mrow><\/mfrac><\/mrow><annotation encoding=\"application\/x-tex\">\\frac{\\partial C}{\\partial t} = D \\frac{\\partial^2 C}{\\partial x^2}<\/annotation><\/semantics><\/math>\u2202t\u2202C\u200b=D\u2202x2\u22022C\u200b<\/p>\n\n\n\n<p>Where:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><em>C<\/em> = concentration<\/li>\n\n\n\n<li><em>t<\/em> = time<\/li>\n\n\n\n<li><em>D<\/em> = diffusion coefficient<\/li>\n\n\n\n<li><em>x<\/em> = depth<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-graphical-output-depth-vs-concentration-for-different-times\">Graphical Output: Depth vs Concentration for Different Times<\/h2>\n\n\n\n<figure class=\"wp-block-image size-full\"><img loading=\"lazy\" decoding=\"async\" width=\"1007\" height=\"910\" src=\"https:\/\/gaeatech.com\/knowledge-center\/wp-content\/uploads\/2026\/04\/image-13.jpg\" alt=\"\" class=\"wp-image-92160\" srcset=\"https:\/\/gaeatech.com\/knowledge-center\/wp-content\/uploads\/2026\/04\/image-13.jpg 1007w, https:\/\/gaeatech.com\/knowledge-center\/wp-content\/uploads\/2026\/04\/image-13-300x271.jpg 300w, https:\/\/gaeatech.com\/knowledge-center\/wp-content\/uploads\/2026\/04\/image-13-768x694.jpg 768w\" sizes=\"auto, (max-width: 1007px) 100vw, 1007px\" \/><\/figure>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-pdf-report\">PDF Report<\/h2>\n\n\n<div class=\"ead-preview\"><div class=\"ead-document\" style=\"position: relative;padding-top: 90%\"><div class=\"ead-iframe-wrapper\"><iframe src=\"\/\/docs.google.com\/viewer?url=https%3A%2F%2Fgaeatech.com%2Fknowledge-center%2Fwp-content%2Fuploads%2F2026%2F04%2Fpollute-example2.pdf&amp;embedded=true&amp;hl=en\" title=\"Embedded Document\" class=\"ead-iframe\" style=\"width: 100%;height: 100%;border: none;position: absolute;left: 0;top: 0;visibility: hidden;\"><\/iframe><\/div>\t\t\t<div class=\"ead-document-loading\" style=\"width:100%;height:100%;position:absolute;left:0;top:0;z-index:10\">\n\t\t\t\t<div class=\"ead-loading-wrap\">\n\t\t\t\t\t<div class=\"ead-loading-main\">\n\t\t\t\t\t\t<div class=\"ead-loading\">\n\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/gaeatech.com\/knowledge-center\/wp-content\/plugins\/embed-any-document\/images\/loading.svg\" width=\"55\" height=\"55\" alt=\"Loader\">\n\t\t\t\t\t\t\t<span>Loading&#8230;<\/span>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t\t<div class=\"ead-loading-foot\">\n\t\t\t\t\t\t<div class=\"ead-loading-foot-title\">\n\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/gaeatech.com\/knowledge-center\/wp-content\/plugins\/embed-any-document\/images\/EAD-logo.svg\" alt=\"EAD Logo\" width=\"36\" height=\"23\"\/>\n\t\t\t\t\t\t\t<span>Taking too long?<\/span>\n\t\t\t\t\t\t<\/div>\n\t\t\t\t\t\t<p>\n\t\t\t\t\t\t\t<div class=\"ead-document-btn ead-reload-btn\" role=\"button\">\n\t\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/gaeatech.com\/knowledge-center\/wp-content\/plugins\/embed-any-document\/images\/reload.svg\" alt=\"Reload\" width=\"12\" height=\"12\"\/> Reload document\t\t\t\t\t\t\t<\/div>\n\t\t\t\t\t\t\t<span>|<\/span>\n\t\t\t\t\t\t\t<a href=\"https:\/\/gaeatech.com\/knowledge-center\/wp-content\/uploads\/2026\/04\/pollute-example2.pdf\" class=\"ead-document-btn\" target=\"_blank\">\n\t\t\t\t\t\t\t\t<img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/gaeatech.com\/knowledge-center\/wp-content\/plugins\/embed-any-document\/images\/open.svg\" alt=\"Open\" width=\"12\" height=\"12\"\/> Open in new tab\t\t\t\t\t\t\t<\/a>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t<\/div>\n\t\t<\/div><\/div>\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-analytical-insight\">Analytical Insight<\/h2>\n\n\n\n<p>Because:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li><strong>Kd = 0 \u2192 no retardation<\/strong><\/li>\n\n\n\n<li><strong>va = 0 \u2192 no advection<\/strong><\/li>\n<\/ul>\n\n\n\n<p>The system behaves as a <strong>pure diffusion medium<\/strong>, meaning:<\/p>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Travel time depends only on <strong>diffusion coefficient and thickness<\/strong><\/li>\n\n\n\n<li>No delay from sorption or flow<\/li>\n\n\n\n<li>Faster breakthrough compared to real soils with adsorption<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-key-results\">Key Results<\/h2>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Rapid contaminant migration relative to sorbing systems<\/li>\n\n\n\n<li>Smooth concentration gradients over time<\/li>\n\n\n\n<li>No retardation effects observed<\/li>\n\n\n\n<li>Steady-state defined by linear gradient<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-conclusions\">Conclusions<\/h2>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Diffusion alone can drive significant contaminant movement<\/li>\n\n\n\n<li>Absence of sorption represents a <strong>worst-case mobility scenario<\/strong><\/li>\n\n\n\n<li>Useful for validating transport models and comparing against more complex cases<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-engineering-insights\">Engineering Insights<\/h2>\n\n\n\n<ul class=\"wp-block-list\">\n<li>This example represents a <strong>baseline condition<\/strong> \u2014 real-world systems usually show slower transport due to:\n<ul class=\"wp-block-list\">\n<li>Sorption (Kd > 0)<\/li>\n\n\n\n<li>Lower effective diffusion<\/li>\n<\/ul>\n<\/li>\n\n\n\n<li>The assumption of a <strong>perfect sink<\/strong> at the base is conservative and ensures:\n<ul class=\"wp-block-list\">\n<li>Maximum downward flux<\/li>\n<\/ul>\n<\/li>\n\n\n\n<li>Dividing the soil into <strong>sub-layers<\/strong> improves numerical accuracy in POLLUTEv10<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<h2 class=\"wp-block-heading\" id=\"h-applications\">Applications<\/h2>\n\n\n\n<ul class=\"wp-block-list\">\n<li>Landfill liner performance comparisons<\/li>\n\n\n\n<li>Risk assessments for conservative contaminants<\/li>\n\n\n\n<li>Model calibration and validation<\/li>\n\n\n\n<li>Teaching and demonstration of diffusion principles<\/li>\n<\/ul>\n\n\n\n<hr class=\"wp-block-separator has-alpha-channel-opacity\"\/>\n\n\n\n<p><\/p>\n\n\n\n<p><\/p>\n","protected":false},"excerpt":{"rendered":"<p>This example is a fundamental case used to demonstrate pure diffusion of a conservative contaminant through soil. Unlike more complex landfill scenarios, this example isolates diffusion-only transport, making it ideal for understanding baseline contaminant migration behavior. Overview of the Scenario In this example, contaminant transport occurs through: Key simplifications: Conceptual Model The system represents a [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":92162,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[858,1632],"tags":[501,1633,24,1634,1630,821,1636,1627,1635],"class_list":["post-92156","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-contaminant-transport-modeling","category-pollute-examples","tag-contaminant-transport","tag-diffusion","tag-environmental-engineering","tag-fick-law","tag-groundwater","tag-hydrogeology","tag-numerical-modeling","tag-pollutev10","tag-soil-modeling"],"yoast_head":"<!-- This site is optimized with the Yoast SEO Premium plugin v27.4 (Yoast SEO v27.4) - https:\/\/yoast.com\/product\/yoast-seo-premium-wordpress\/ -->\n<title>POLLUTEv10 Example 2: Pure Diffusion Fundamentals - Knowledge Center<\/title>\n<meta name=\"description\" content=\"Explore the POLLUTEv10 Example 2: Pure Diffusion Modeling in Soil. 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